• We invented supercritical hydrothermal synthesis method for the synthesis of organic modified nanoparticles (NPs). Under the supercritical state, the organic molecules and metal salt aqueous solutions are miscible and water molecule works as an acid/base catalyst for the reactions. Organic-inorganic conjugate NPs can be synthesized under this condition. This hybrid NPs show high affinity with the organic solvent or the polymer matrix, which leads to fabricate the organic inorganic hybrid nanomaterials with the trade-off function (super hybird nanomaterials). These hybrid materials of polymer and ceramics fabricated with NPs achieve both high thermal conductivity and easy thin film flexible fabrication, namely trade-off function.

For example, by the surface modification of BN particles by supercritical method, affinity of BN and polymers could be improved, so that high BN content of hybrid materials, thus high thermal conductivity materials, could be synthesized. Also by dispersing high refractive index NPs like TiO2 or ZrO2 into polymers transparently, we can tune the refractive index of the polymers. CeO2 nanoparticles are expected to be used for high performance catalysts. To transfer those supercritical fluid nano technologies, a consortium was launched with more than 70 companies.

• Intergranular degradation often results in decreased lifetime, reliability and economical efficiency of polycrystalline materials. In spite of persistent efforts to prevent such degradation, its complete suppression has not yet been achieved. Grain boundary studies have revealed that coincidence-site-lattice (CSL) boundaries have stronger resistance to intergranular degradations than random boundaries. The concept of ‘grain boundary design and control' has been refined as grain boundary engineering (GBE). GBEed materials which are characterized by high frequencies of CSL boundaries are resistant to intergranular degradations. Our group has achieved very high frequencies of CSL boundaries in commercial stainless steels by GBE. GBEed stainless steels showed significantly stronger resistance to intergranular corrosion (see Figs. 1 and 2), weld-decay, knife-line attack, stress corrosion cracking, liquid-metal embrittlement, radiation damage, etc. and much longer creep life (see Fig. 3) than the unGBEed ones.

By using this GBE processing, we expect to conduct effective collaborative research in related fields.

• Multifunctional molecular-assemblies and hybrid organic - inorganic materials are examined from the viewpoint of structural freedom of organic molecules. The spin and electronic states of molecular-assemblies are designed in terms of electrical conductivity, magnetism, and ferroelectricity. Diverse molecular assemblies from single crystal, plastic crystal, liquid crystal, gel, to Langmuir-Blodgett film are our research targets, which were hybridized with inorganic gigantic clusters and metal nanoparticles. We are prepared to provide academic consultations to companies interested in our research.

• We are doing theoretical research on electrical conductivity in magnetoresistive devices using highly spin-polarized materials. The aim is to achieve very functional spintronics devices such as read-out heads for ultrahigh-density magnetic recording and non-volatile spin memories. We also investigate magnetoresistive devices using perpendicularly magnetized materials to ensure endurance against thermal fluctuations of the magnetization. We successfully achieve a guideline for improvement of the magnetoresistive performance by designing the crystal structure at the interface between ferromagnets and oxides theoretically.
• We believe that first-principles calculations, which need no empirical parameter, play a very important role in research and development of various materials. Please contact us if you want to collaborate with us.

• Highly-sensitive NMR technique has been developed by manipulation polarization of nuclear spins via control of transport characteristics in GaAs and InSb quantum structures. This highly-sensitive NMR can be applied to two-dimensional and nanostructures. Furthermore, ideal gate controllability has been demonstrated in InSb quantum structures with Al2 O3 dielectrics. More importantly, the concept of generalized coherence time was introduced, where noise characteristics felt by nuclear spins can be measured including their frequency dependence. This concept will bring about a change in all nuclear-spin related measurements.

Next generation InSb devices based on good gate controllability. Various nuclear-spin based measurements and NMR utilizing the concept of generalized coherence time. Highly-sensitive NMR is now important for fundamental physics studies. In the future, it will contribute to quantum information processing.

• We challenge to fabricate in vacuum-stabilized micro/nano-scale liquid materials, explore their novel chemicophysical properties and develop their vacuum processing applications. The representative examples include ultra thin film ionic liquid on the nanometer scale and advanced vapor-liquid-solid growth (VLS) of inorganic/organic materials, such as 4H- and 3C-SiC films, single crystal pentacene and a porous polymer film of plolythiophene.

Our research outcomes will contribute to the following research and development:
1) a next-generation semiconductor process with the merits of the wet process
2) a new purification process of organic semiconductors, by which some part of inorganic semiconductor materials would be replaced in response to the present world-wide shortage of semiconductors.

In addition, the consultation of how to use our ionic liquid-assisted vapor growth method in attempt to obtain organic single crystals is welcome.